Sodium Chloride → HCID 178499521, 화합물

HRID 2064638노트

반응식

HRID 2064638 반응식
[CH3:1][O:2][CH:3]([O:8][CH3:9])[C:4](=O)[CH:5]=[CH2:6].O.[NH2:11][NH2:12].[Cl-].[Na+]>O>[CH3:1][O:2][CH:3]([O:8][CH3:9])[C:4]1[CH:5]=[CH:6][NH:12][N:11]=1

참가 물질

5

반응물 3

HCID 5234Sodium ChlorideHCID 24654Hydrazine hydrate (1:1)HCID 224778181,1-Dimethoxybut-3-en-2-one

생성물 1

HCID 178499521HCID 178499521, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A stirred solution of 1,1-dimethoxy-but-3-en-2-one in water (300 μL) was treated dropwise with hydrazine hydrate (21 mL). After standing at room temperature overnight the reaction mixture was treated with sodium chloride (108 g) and the mixture was then extracted with methyl-t-butylether (200 mL then 100 mL). The combined extracts were dried with magnesium sulfate and then evaporated to give 1H-pyrazol-3-carbaldehyde dimethyl acetal as a light brown oil (18.47 g).

후처리

  1. extractionthe mixture was then extracted with methyl-t-butylether (200 mL
  2. dry with materialThe combined extracts were dried with magnesium sulfate
  3. customevaporated

출처 및 근거

ORD 기록
ord-caba686c7eda47d4a095333e2e89df10
출처 데이터셋
uspto-grants-2012_10
특허 번호
US08288425B2

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