N-bromobutanimide → 3-bromo-2-hydroxy-5-methylbenzaldehyde

HRID 2069918노트

반응식

HRID 2069918 반응식
[CH3:1][C:2]1[CH:9]=[C:6]([CH:7]=[O:8])[C:5]([OH:10])=[CH:4][CH:3]=1.[Br:11]N1C(=O)CCC1=O>>[Br:11][C:4]1[C:5]([OH:10])=[C:6]([CH:9]=[C:2]([CH3:1])[CH:3]=1)[CH:7]=[O:8]

참가 물질

3

반응물 2

HCID 67184N-bromobutanimideHCID 69184Benzaldehyde, 2-hydroxy-5-methyl-

생성물 1

HCID 27570153-bromo-2-hydroxy-5-methylbenzaldehyde수율 76.1%

실험 절차

Proceeding as in Reference 9, but substituting 5-methyl salicylaldehyde (3 g, 22 mmol) and N-bromosuccinimide (4.7 g, 26.4 mmol), gave 3-bromo-2-hydroxy-5-methylbenzaldehyde (3.6 g).

출처 및 근거

ORD 기록
ord-64e6b6d30812436f9f62cbaf68f86fee
출처 데이터셋
uspto-grants-2012_10
특허 번호
US08299110B2

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