4-{[(2,2-Dichlorocyclopropyl)methyl]sulfanyl}-2-nitroaniline → HCID 20532837, 화합물

HRID 2071430노트

반응식

HRID 2071430 반응식
[Cl:1][C:2]1([Cl:17])[CH2:4][CH:3]1[CH2:5][S:6][C:7]1[CH:13]=[CH:12][C:10]([NH2:11])=[C:9]([N+:14]([O-])=O)[CH:8]=1>C(O)C.O=[Pt]=O>[Cl:17][C:2]1([Cl:1])[CH2:4][CH:3]1[CH2:5][S:6][C:7]1[CH:13]=[CH:12][C:10]([NH2:11])=[C:9]([NH2:14])[CH:8]=1

참가 물질

4

반응물 1

HCID 205328394-{[(2,2-Dichlorocyclopropyl)methyl]sulfanyl}-2-nitroaniline

생성물 1

HCID 20532837HCID 20532837, 화합물

시약·촉매·용매 2

HCID 345198Adams' catalyst촉매HCID 702Ethanol용매

실험 절차

A mixture of 8.8 g (0.03 mole) of 4-[(2,2-dichlorocyclopropyl)methyl]thio-2-nitroaniline and 0.6 g of PtO2 in 200 ml of absolute ethanol is reduced on the Parr hydrogenator at 50 psi until the theoretical amount of H2 is absorbed. The mixture is filtered and the solvent is removed in vacuo to yield a dark oil.

후처리

  1. customis absorbed
  2. filtrationThe mixture is filtered
  3. customthe solvent is removed in vacuo
  4. customto yield a dark oil

출처 및 근거

ORD 기록
ord-7439281ecbd54d4fa2c5e3e5f497e190
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04046908

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