Benzoyl Peroxide → 2-(4-[1-Bromoethyl]phenyl)benzoxazole

HRID 2071484노트

반응식

HRID 2071484 반응식
[CH2:1]([C:3]1[CH:8]=[CH:7][C:6]([C:9]2[O:10][C:11]3[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=3[N:13]=2)=[CH:5][CH:4]=1)[CH3:2].[Br:18]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:18][CH:1]([C:3]1[CH:8]=[CH:7][C:6]([C:9]2[O:10][C:11]3[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=3[N:13]=2)=[CH:5][CH:4]=1)[CH3:2]

참가 물질

5

반응물 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimide2회HCID 39933832-(4-Ethyl-phenyl)-benzooxazole

생성물 1

HCID 234591652-(4-[1-Bromoethyl]phenyl)benzoxazole

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

To a solution of 7.1 gm. of 2-(4-ethylphenyl)benzoxazole in 125 cc. of carbon tetrachloride is added 6.2 gm. of N-bromosuccinimide and 50 mg. of benzoyl peroxide. The mixture is refluxed for about one half hour at which time the N-bromosuccinimide was consumed. Filtration followed by concentration of the filtrate gives 2-(4-[1-bromoethyl]phenyl)benzoxazole, m.p. 128°-131° C.

후처리

  1. customwas consumed
  2. filtrationFiltration

출처 및 근거

ORD 기록
ord-7d2dd70ead584f14a799956666fe29dc
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04046905

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