Phenol → 9,10-Anthracenedione, 1-amino-4,5-dihydroxy-8-nitro-

HRID 2071671

반응식

HRID 2071671 반응식
[OH:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[C:9]([N+:18]([O-:20])=[O:19])[CH:10]=[CH:11][C:12]=3[OH:17])[C:7](=[O:21])[C:6]=2[C:5]([N+:22]([O-])=O)=[CH:4][CH:3]=1.C1(O)C=CC=CC=1.N1CCOCC1>CO>[NH2:22][C:5]1[C:6]2[C:7](=[O:21])[C:8]3[C:13](=[C:12]([OH:17])[CH:11]=[CH:10][C:9]=3[N+:18]([O-:20])=[O:19])[C:14](=[O:16])[C:15]=2[C:2]([OH:1])=[CH:3][CH:4]=1

참가 물질

5

반응물 3

HCID 996PhenolHCID 8083Morpholine2회HCID 33784401,8-Dinitro-4,5-dihydroxyanthraquinone

생성물 1

HCID 54840799,10-Anthracenedione, 1-amino-4,5-dihydroxy-8-nitro-

시약·촉매·용매 1

HCID 887Methanol용매

반응 조건

온도
150 °C

실험 절차

8.25 parts of 1,8-dihydroxy-4,5-dinitroanthraquinone is heated in 40 parts of phenol in the presence of 1 part of morpholine for 3 hours at 140° to 150° C. Then another 1 part of morpholine is added and the whole is heated for 1 hour at 150° C. The reaction mixture is allowed to cool to 60° C, 80 parts of methanol is added and the precipitated reaction product is suction filtered. The filter residue is washed with hot water and dried. 4.9 parts of 1-amino-8-nitro-4,5-dihydroxyanthraquinone is obtained.

후처리

  1. temperatureto cool to 60° C
  2. customthe precipitated reaction product
  3. filtrationfiltered
  4. washThe filter residue is washed with hot water
  5. customdried

출처 및 근거

ORD 기록
ord-b819bbdb779e4185b9a675fc9b6300d6
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04048199

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