Allyl chloride → 2-Bromo-1-chloropropane

The same process as in example 2 was carried out, but the cyclohexane was replaced by 3-bromo-1-chloropropane. The reaction developed in the same way. After 30 minutes of irradiation at 22° C, 90% of allyl chloride had been converted. The reaction product was degassed and the unreacted allyl chloride was distilled. The remaining product was formed by 3-bromo-1-chloropropane (solvent + formed product) and about 3% of 2-bromo-1-chloropropane. This operation has the advantage of making the solvent distillation unnecessary.

1. customAfter 30 minutes of irradiation at 22° C
2. customThe reaction product was degassed
3. distillationthe unreacted allyl chloride was distilled

ORD 기록

ord-fd729aa701f2427aaa34fce67080442c

출처 데이터셋

uspto-grants-1977_09

DOI

10.6084/m9.figshare.5104873.v1

특허 번호

US04049516