1,2-Dichlorobenzene → Hexachloroindene

HRID 2072170

반응식

HRID 2072170 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[Cl:8].[Cl:9][C:10](Cl)(Cl)[C:11]([Cl:15])=[C:12](Cl)[Cl:13].[Cl:18]C(Cl)=C(Cl)Cl>>[Cl:1][C:2]1[CH:7]=[C:6]2[C:5]([C:10]([Cl:9])=[C:11]([Cl:15])[CH:12]2[Cl:13])=[C:4]([Cl:18])[C:3]=1[Cl:8]

참가 물질

4

반응물 3

HCID 72391,2-DichlorobenzeneHCID 159021,1,2,3,3,3-Hexachloro-1-propeneHCID 31373Tetrachloroethylene

생성물 1

HCID 53971155Hexachloroindene수율 48.7%

반응 조건

온도
125 °C

실험 절차

A mixture containing 29.4 grams (0.2 mole), of ortho-dichlorobenzene, 50 grams (0.2 moles) of hexachloropropylene and 2.5 grams of ferric chloride in 250 milliliters of perchloroethylene was heated and stirred by the process of Example I for about 4 hours at reflux (125° C.). The reaction mixture was then washed with concentrated hydrochloric acid, then water and distilled to give a 48.7% yield of hexachloroindene. The product was confirmed by infrared and NMR spectra analysis as structured.

후처리

  1. additionA mixture containing 29.4 grams (0.2 mole)
  2. washThe reaction mixture was then washed with concentrated hydrochloric acid
  3. distillationwater and distilled

출처 및 근거

ORD 기록
ord-ebe79f31ccfc476ca69a935b53df9376
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04049727

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