Ethanol → HCID 501147, 화합물

HRID 2072254노트

반응식

HRID 2072254 반응식
[C:1]1([CH:7](Cl)[CH2:8][CH2:9][CH3:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na].[SH:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][N+:15]=1[O-:20].C(O)C>O>[C:1]1([CH:7]([S:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][N+:15]=2[O-:20])[CH2:8][CH2:9][CH3:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

6

반응물 4

HCID 702EthanolHCID 524322Benzene, (1-chlorobutyl)HCID 5360545SodiumHCID 178526253HCID 178526253, 화합물

생성물 1

HCID 501147HCID 501147, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A mixture of 16.9 gms (0.1 mol) of 1-phenylbutylchloride, 36 gms of a 40% aqueous solution of the sodium salt of 2-mercaptopyridine N-oxide (0.1 mol) and 50 ml of ethanol was warmed and stirred at 50° to 60° C. for 2.5 hours. The cooled reaction mixture was poured into 500 ml of water with agitation. The precipitated product was filtered, washed with water and dried. After recrystallization for ethanol a yield of 10 gms (45% theory) of white crystals was obtained.

후처리

  1. temperaturewas warmed
  2. customThe cooled reaction mixture
  3. filtrationThe precipitated product was filtered
  4. washwashed with water
  5. customdried
  6. customAfter recrystallization for ethanol a yield of 10 gms (45% theory) of white crystals
  7. customwas obtained

출처 및 근거

ORD 기록
ord-15871f206bdd480fb48552dbb71c822a
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04050921

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