L-(-)-Sorbose → Sorbosone, L-

HRID 2073159

반응식

HRID 2073159 반응식
[OH:1][CH2:2][C:3]([C@H:5]([C@@H:7]([C@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])=[O:4].P([O-])([O-])([O-])=O.[K+].[K+].[K+]>C[N+]1C2C(=CC=CC=2)N=C2C=1C=CC=C2.COS([O-])(=O)=O>[CH2:11]([OH:12])[C@H:9]([OH:10])[C@@H:7]([OH:8])[C@H:5]([OH:6])[C:3]([CH:2]=[O:1])=[O:4]

참가 물질

4

반응물 2

HCID 6904L-(-)-Sorbose3회HCID 62657Potassium Phosphate, Tribasic

생성물 1

HCID 10921067Sorbosone, L-

시약·촉매·용매 1

HCID 9285Phenazine Methosulfate용매

실험 절차

The reaction mixture containing 400 ml of purified membrane-bound L-sorbose dehydrogenase (total activity, 120 units), as prepared by the manner as described in steps (1) to (5) of Example 1, 50 ml of 0.5M potassium phosphate buffer (pH 6.0). 50 ml of 1M L-sorbose solution and 10 ml of 0.2M phenazine methosulfate solution was incubated at 30° C. with gentle shaking. As a result, L-sorbosone was formed with the rate of 224 mg/hr.

후처리

  1. customas prepared by the manner
  2. customwas incubated at 30° C. with gentle shaking

출처 및 근거

ORD 기록
ord-9f0bf67697f44edd8787cd0b3876adcd
출처 데이터셋
uspto-grants-1990_04
특허 번호
US04916069

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