Water → N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

HRID 2105290노트

반응식

HRID 2105290 반응식
[C:1]1([CH3:13])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9](Cl)(=[O:11])=[O:10].[CH3:14][C:15](=[N:17][OH:18])[CH3:16].O>N1C=CC=CC=1>[CH3:13][C:1]1[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9]([O:18][N:17]=[C:15]([CH3:16])[CH3:14])(=[O:11])=[O:10]

참가 물질

5

반응물 3

HCID 962WaterHCID 130462-Mesitylenesulfonyl chlorideHCID 67180Acetone, oxime

생성물 1

HCID 279802N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

시약·촉매·용매 1

HCID 1049Pyridine용매

실험 절차

To a solution of mesitylenesulfonyl chloride (2.0 g, 9.05 mmol) in pyridine (30 mL) was added acetone oxime (0.67 g, 9.05 mmol), and the solution was stirred under N2 for 16 hours. It was poured into 500 ml of water and stirred for 1 hour. The precipitate was filtered and dried. Acetone O-(2,4,6-trimethylphenylsulfonyl)oxime was obtained as white powder (57.6%) yield.

후처리

  1. stirringstirred for 1 hour
  2. filtrationThe precipitate was filtered
  3. customdried

출처 및 근거

ORD 기록
ord-8deaa3c6c49246ac97ccd16d5fb37fbf
출처 데이터셋
uspto-grants-2009_08
특허 번호
US07579340B2

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