Suberic acid → Oxonane-2,9-dione

HRID 217095

반응식

HRID 217095 반응식
[C:1]([OH:12])(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([OH:10])=O>CC(OC(C)=O)=O>[O:12]1[C:1](=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]1=[O:10]

참가 물질

3

반응물 1

HCID 10457Suberic acid

생성물 1

HCID 9543534Oxonane-2,9-dione

시약·촉매·용매 1

HCID 7918Acetic Anhydride용매

실험 절차

Under N2 atmosphere 50 g suberic acid and 100 ml acetanhydride were refluxed for 2 hours. The solvent was evaporated and 200 ml acetonitrile were added to the residue and the mixture was kept in a freezer over night. Then the mixture was fritted and the resulting residue was washed with 50 ml acetonitrile and dried.

후처리

  1. customThe solvent was evaporated
  2. addition200 ml acetonitrile were added to the residue
  3. waitthe mixture was kept in a freezer over night
  4. washthe resulting residue was washed with 50 ml acetonitrile
  5. customdried

출처 및 근거

ORD 기록
ord-d4634b1c94844c949baa8b06a896ae0b
출처 데이터셋
uspto-grants-2012_06
특허 번호
US08193246B2

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