Ammonia → 1-Amino-4-hydroxyanthraquinone

HRID 21819

반응식

HRID 21819 반응식
[OH:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5](O)=[CH:4][CH:3]=1.OCC(=O)C.[NH3:24].[OH-].[Na+]>O>[NH2:24][C:5]1[C:6]2[C:7](=[O:17])[C:8]3[C:13](=[CH:12][CH:11]=[CH:10][CH:9]=3)[C:14](=[O:16])[C:15]=2[C:2]([OH:1])=[CH:3][CH:4]=1

참가 물질

6

반응물 4

HCID 222AmmoniaHCID 6688QuinizarinHCID 8299HydroxyacetoneHCID 14798Sodium Hydroxide

생성물 1

HCID 83231-Amino-4-hydroxyanthraquinone수율 71.1%

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
100 °C

실험 절차

70 ml of water, 26.5 g of 1,4-dihydroxyanthraquinone, 1.2 g of hydroxyacetone, 80 g of 25% strength by weight aqueous ammonia solution and 20 g of 50% strength by weight sodium hydroxide solution were introduced into a pressure-resistant apparatus. The apparatus was then sealed pressure-tight and its contents were heated to 100° C., giving rise to an autogenous pressure of 2.7 bar. The reaction mixture was held under these conditions for 3 h, then cooled down and depressurized. The precipitate found was filtered off with suction, washed salt-free with water and dried to leave 15.8 g of 1-amino-4-hydroxyanthraquinone (purity according to GC: 71.1%).

후처리

  1. customgiving rise to an autogenous pressure of 2.7 bar
  2. temperaturecooled down
  3. filtrationThe precipitate found was filtered off with suction
  4. washwashed salt-free with water
  5. customdried

출처 및 근거

ORD 기록
ord-1dd1e325fda84c2eaee9efbc8543d169
출처 데이터셋
uspto-grants-1995_06
특허 번호
US05424461

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