홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Glycidyl methacrylate → Propylene glycol methyl ether acetate

HRID 2191184
노트
인쇄 미리보기

반응식

HRID 2191184 반응식
[C:1]([O:5][CH:6]([O:8][CH2:9][CH3:10])[CH3:7])(=[O:4])[CH:2]=[CH2:3].[C:11]([O:16][CH2:17][CH:18]1[O:20][CH2:19]1)(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:21]([O:26][CH2:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)(=[O:25])[C:22]([CH3:24])=[CH2:23].N(C(C)(CC)C([O-])=O)=N[C:36](C)(CC)C([O-])=O>CCCCCCC.C(C(C)=O)C(C)C>[C:1]([O:5][CH:6]([O:8][CH2:9][CH3:10])[CH3:7])(=[O:4])[CH:2]=[CH2:3].[C:11]([O:16][CH2:17][CH:18]1[O:20][CH2:19]1)(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:21]([O:26][CH2:27][C:28]1[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=1)(=[O:25])[C:22]([CH3:24])=[CH2:23].[C:11]([O:16][CH:17]([CH3:36])[CH2:18][O:20][CH3:19])(=[O:15])[CH3:12]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

8

반응물 4

HCID 7837Glycidyl methacrylateHCID 17236Benzyl methacrylateHCID 205502781-Ethoxyethyl acrylateHCID 219175032,2'-Azobis(methyl 2-methylpropanate)

생성물 2

HCID 7946Propylene glycol methyl ether acetateHCID 866432091-Ethoxyethyl acrylate glycidyl methacrylate benzyl methacrylate

시약·촉매·용매 2

HCID 7909Methyl Isobutyl Ketone용매HCID 8900Heptane용매

실험 절차

Into a 500 ml-volume three-neck flask, 43.3 g (0.3 mol) of 1-ethoxyethyl acrylate, 25.6 g (0.18 mol) of glycidyl methacrylate, 21.2 g (0.12 mol) of benzyl methacrylate and 300 ml of methyl isobutyl ketone were charged. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) was added thereto as a radical polymerization initiator, and polymerization was allowed to proceed at 80° C. for 6 hours in a nitrogen stream. The reaction solution was cooled and then poured in a large amount of heptane to precipitate a polymer. The crystal was collected by filtration and dissolved in propylene glycol monomethyl ether acetate, and heptane and methyl isobutyl ketone contained in the solution were removed by distillation under reduced pressure to obtain Polymer A-4 (1-ethoxyethyl acrylate/glycidyl methacrylate/benzyl methacrylate) as a propylene glycol monomethyl ether acetate solution.

후처리

  1. customas a radical polymerization initiator, and polymerization
  2. temperatureThe reaction solution was cooled
  3. customto precipitate a polymer
  4. filtrationThe crystal was collected by filtration
  5. dissolutiondissolved in propylene glycol monomethyl ether acetate
  6. customwere removed by distillation under reduced pressure

출처 및 근거

ORD 기록
ord-22732568e0744e97848c62fd36f5c234
출처 데이터셋
uspto-grants-2012_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08329380B2

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차후처리출처 및 근거반응 노트