Stannous Chloride → 5-Bromo-2-phenoxyaniline

HRID 2197841노트

반응식

HRID 2197841 반응식
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[C:4]([N+:15]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[C:4]([NH2:15])[CH:3]=1

참가 물질

3

반응물 2

HCID 24479Stannous ChlorideHCID 161094494-Bromo-2-nitro-1-phenoxybenzene

생성물 1

HCID 161094555-Bromo-2-phenoxyaniline수율 100%

실험 절차

The product from Example 124a (6.6 g, 22.5 mmol) was reduced with SnCl2 following the procedure from Example 1f giving the title compound as a brown oil (5.9 g, 100%).

출처 및 근거

ORD 기록
ord-d43867c70252400aa567728c2e429554
출처 데이터셋
uspto-grants-2012_12
특허 번호
US08338605B2

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