Stannous Chloride → 3-(2-Amino-4-chloro-phenoxy)-benzamide

HRID 2197915노트

반응식

HRID 2197915 반응식
[Cl:1][C:2]1[CH:17]=[CH:16][C:5]([O:6][C:7]2[CH:8]=[C:9]([CH:13]=[CH:14][CH:15]=2)[C:10]([NH2:12])=[O:11])=[C:4]([N+:18]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[NH2:18][C:4]1[CH:3]=[C:2]([Cl:1])[CH:17]=[CH:16][C:5]=1[O:6][C:7]1[CH:8]=[C:9]([CH:13]=[CH:14][CH:15]=1)[C:10]([NH2:12])=[O:11]

참가 물질

3

반응물 2

HCID 24479Stannous ChlorideHCID 684618453-(4-Chloro-2-nitro-phenoxy)-benzamide

생성물 1

HCID 284018643-(2-Amino-4-chloro-phenoxy)-benzamide수율 120.2%

실험 절차

The product from Example 171a (0.56 g, 1.9 mmol) was reacted with SnCl2 following the procedure described in Example 1f to give the title compound (0.60 g, 83%).

출처 및 근거

ORD 기록
ord-49760372eee34ab8adb62e3d6755317e
출처 데이터셋
uspto-grants-2012_12
특허 번호
US08338605B2

반응 노트

불러오는 중…