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Trifluoroacetamide → N-[(R)-Cyclopropyl(4-nitrophenyl)oxidosulphanylidene]-2,2,2-trifluoroacetamide

HRID 2199510
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HRID 2199510 반응식
[CH:1]1([S:4]([C:6]2[CH:11]=[CH:10][C:9]([N+:12]([O-:14])=[O:13])=[CH:8][CH:7]=2)=[O:5])[CH2:3][CH2:2]1.[F:15][C:16]([F:21])([F:20])[C:17]([NH2:19])=[O:18].C(O)(=O)C.C(O)(=O)C.IC1C=CC=CC=1.[O-2].[Mg+2]>C(Cl)Cl.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.[Rh+2].[Rh+2]>[CH:1]1([S:4]([C:6]2[CH:11]=[CH:10][C:9]([N+:12]([O-:14])=[O:13])=[CH:8][CH:7]=2)(=[N:19][C:17](=[O:18])[C:16]([F:21])([F:20])[F:15])=[O:5])[CH2:3][CH2:2]1
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참가 물질

7

반응물 4

HCID 67717TrifluoroacetamideHCID 6850729Magnesium monoxideHCID 12217721Iodo benzene diacetateHCID 595508341-(Cyclopropanesulfinyl)-4-nitrobenzene

생성물 1

HCID 56949254N-[(R)-Cyclopropyl(4-nitrophenyl)oxidosulphanylidene]-2,2,2-trifluoroacetamide수율 78%

시약·촉매·용매 2

HCID 152122
Dirhodium tetraacetate
촉매
HCID 6344Dichloromethane용매

실험 절차

A suspension of (RS)-1-cyclopropanesulphinyl-4-nitrobenzene, trifluoroacetamide, iodobenzene diacetate and magnesium oxide in DCM was admixed, under argon, with rhodium(II) acetate dimer and stirred overnight at room temperature. The mixture was filtered off with suction over Celite and concentrated by evaporation. The remaining residue was purified by means of chromatography (hexane/acetic ester 2:1) (yield: 78%).

후처리

  1. filtrationThe mixture was filtered off with suction over Celite
  2. concentrationconcentrated by evaporation
  3. customThe remaining residue was purified by means of chromatography (hexane/acetic ester 2:1) (yield: 78%)

출처 및 근거

ORD 기록
ord-5553505048354ffa84a33f9a9e44629f
출처 데이터셋
uspto-grants-2016_06
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US09359306B2

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