Surfactin → HCID 131735968, 화합물

HRID 2208628노트

반응식

[Cl-].[Ca+2:2].[Cl-].[Na].[CH3:5][CH:6]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C@H:17]1[O:49][C:47](=[O:48])[C@H:46]([CH2:50][CH:51]([CH3:53])[CH3:52])[NH:45][C:43](=[O:44])[C@@H:42]([CH2:54][CH:55]([CH3:57])[CH3:56])[NH:41][C:39](=[O:40])[C@H:38]([CH2:58][C:59]([OH:61])=[O:60])[NH:37][C:35](=[O:36])[C@H:34]([CH:62]([CH3:64])[CH3:63])[NH:33][C:31](=[O:32])[C@@H:30]([CH2:65][CH:66]([CH3:68])[CH3:67])[NH:29][C:27](=[O:28])[C@H:26]([CH2:69][CH:70]([CH3:72])[CH3:71])[NH:25][C:23](=[O:24])[C@H:22]([CH2:73][CH2:74][C:75]([OH:77])=[O:76])[NH:21][C:19](=[O:20])[CH2:18]1)[CH3:7].CC(CCCCCCCCC[C@H]1OC(=O)[C@H](CC(C)C)NC(=O)[C@@H](CC(C)C)NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](C(C)C)NC(=O)[C@@H](CC(C)C)NC(=O)[C@H](CC(C)C)NC(=O)[C@H](CCC(O)=O)NC(=O)C1)C>>[Ca:2].[CH3:7][CH:6]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C@H:17]1[O:49][C:47](=[O:48])[C@H:46]([CH2:50][CH:51]([CH3:52])[CH3:53])[NH:45][C:43](=[O:44])[C@@H:42]([CH2:54][CH:55]([CH3:56])[CH3:57])[NH:41][C:39](=[O:40])[C@H:38]([CH2:58][C:59]([OH:61])=[O:60])[NH:37][C:35](=[O:36])[C@H:34]([CH:62]([CH3:63])[CH3:64])[NH:33][C:31](=[O:32])[C@@H:30]([CH2:65][CH:66]([CH3:68])[CH3:67])[NH:29][C:27](=[O:28])[C@H:26]([CH2:69][CH:70]([CH3:72])[CH3:71])[NH:25][C:23](=[O:24])[C@H:22]([CH2:73][CH2:74][C:75]([OH:77])=[O:76])[NH:21][C:19](=[O:20])[CH2:18]1)[CH3:5]

참가 물질

반응물 3

HCID 443592Surfactin

HCID 5284359Calcium Chloride

HCID 131735969Sodium surfactin

생성물 1

HCID 131735968HCID 131735968, 화합물

실험 절차

Photographs taken before and after adding calcium ion to a 0.05 mass % aqueous sodium surfactin solution are demonstrated as FIG. 1 for reference. As shown in FIG. 1(1), sodium surfactin was dissolved completely before addition of calcium ion. The white part in the upper part of FIG. 1(1) was composed of bubbles formed by sodium surfactin as a surfactant. On the one hand, as shown in FIG. 1(2), when 1 mL of a saturated aqueous calcium chloride solution was added to about 150 mL of a 0.05 mass % aqueous sodium surfactin solution, it was observed that the bubbles disappeared, and surfactin became insolubilized by calcium ion to form calcium surfactin and deposited in the lower part.

출처 및 근거

ORD 기록: ord-466f6805ad8a4ca7a95e8867918a45af
출처 데이터셋: uspto-grants-2016_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09376547B2

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