Acenaphthene → Acenaphthylene, dodecahydro-

HRID 2231789

반응식

HRID 2231789 반응식
[CH2:1]1[C:11]2=[C:12]3[C:7](=[CH:8][CH:9]=[CH:10]2)[CH:6]=[CH:5][CH:4]=[C:3]3[CH2:2]1>[Pd]>[CH2:1]1[CH:11]2[CH:12]3[CH:7]([CH2:8][CH2:9][CH2:10]2)[CH2:6][CH2:5][CH2:4][CH:3]3[CH2:2]1

참가 물질

3

반응물 1

HCID 6734Acenaphthene

생성물 1

HCID 102215Acenaphthylene, dodecahydro-수율 99.6%

시약·촉매·용매 1

HCID 23938Palladium촉매

실험 절차

Acenaphthene was hydrogenated by the same procedure as in Example 1 except that the catalyst was replaced by a 5% Pd/C catalyst and reaction was effected at 160° C. for 6 hours. No substantial change was observed in the distribution of reaction products at the end of 4 hour reaction. Perhydroacenaphthene was finally obtained in a yield of 99.6%. The yields of Nos. 1 to 4 isomers were 33.5%, 11.8%, 24.5%, and 29.7%, respectively.

후처리

  1. customNo substantial change was observed in the distribution of reaction products at the end of 4 hour reaction

출처 및 근거

ORD 기록
ord-2fa212b42f7747d288d4f74fe660711c
출처 데이터셋
uspto-grants-1988_11
특허 번호
US04783565

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