Acetic Acid → Carboxyphenylstearic acid

HRID 223780

반응식

HRID 223780 반응식
[C:1]1(C)[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH:7]([CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[C:8]([OH:10])=[O:9].O=O.[C:30]([OH:33])(=[O:32])C>C([O-])(=O)C.[Co+2].C([O-])(=O)C>[C:30]([C:7]([C:2]1[CH:1]=[CH:6][CH:5]=[CH:4][CH:3]=1)([CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[C:8]([OH:10])=[O:9])([OH:33])=[O:32]

참가 물질

5

반응물 3

HCID 176Acetic AcidHCID 977OxygenHCID 223239372-(2-Methylphenyl)octadecanoic acid

생성물 1

HCID 70555697Carboxyphenylstearic acid

시약·촉매·용매 1

HCID 6277Cobalt diacetate촉매

반응 조건

온도
105 °C

실험 절차

One-hundred and eight grams of the distilled tolylstearic acid was charged to a one-liter stirred Parr autoclave with 400 mls acetic acid and 50 gms cobalt (II) acetate. The reactor was sealed, heated to 105° C. and pressured with oxygen to 350 psig.

후처리

  1. customThe reactor was sealed

출처 및 근거

ORD 기록
ord-9cb21e62965c4cd8bd3aea7918dbe682
출처 데이터셋
uspto-grants-1982_10
특허 번호
US04356315

연결된 노트

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