Cyclohexanone → N-cyclohexylidene(3-phenoxybenzylamine)

HRID 224273

반응식

HRID 224273 반응식
[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH2:11][NH2:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:16]1(=O)[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17]1>>[C:16]1(=[N:12][CH2:11][C:10]2[CH:13]=[CH:14][CH:15]=[C:8]([O:1][C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH:9]=2)[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17]1

참가 물질

3

반응물 2

HCID 7967CyclohexanoneHCID 10948363-Phenoxy-benzylamine

생성물 1

HCID 23332475N-cyclohexylidene(3-phenoxybenzylamine)수율 58.8%

실험 절차

The procedure is carried out as described in Example 1(b) but with the use of 50 g (0.25 mol) of 3-phenoxybenzylamine and 25 g (0.255 mol) of cyclohexanone. Distillation leaves 41 g (0.147 mol) of N-cyclohexylidene(3-phenoxybenzylamine), corresponding to a yield of 58.7% of theory; b.p. 135°-136° C./4 Pa.

후처리

  1. distillationDistillation

출처 및 근거

ORD 기록
ord-8c9b2432a9be468692207c8de8a277d2
출처 데이터셋
uspto-grants-1980_11
특허 번호
US04231962

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