Acetic Anhydride → HCID 23332924, 화합물

HRID 224401노트

반응식

HRID 224401 반응식
[OH:1][C:2]1[CH:3]=[CH:4][C:5]2[O:10][CH:9]([C:11]([Cl:14])([Cl:13])[Cl:12])[O:8][CH:7]([C:15]([Cl:18])([Cl:17])[Cl:16])[C:6]=2[CH:19]=1.[C:20](OC(=O)C)(=[O:22])[CH3:21]>O>[C:20]([O:1][C:2]1[CH:3]=[CH:4][C:5]2[O:10][CH:9]([C:11]([Cl:12])([Cl:13])[Cl:14])[O:8][CH:7]([C:15]([Cl:18])([Cl:17])[Cl:16])[C:6]=2[CH:19]=1)(=[O:22])[CH3:21]

참가 물질

4

반응물 2

HCID 7918Acetic AnhydrideHCID 233329442,4-Bis(trichloromethyl)-2H,4H-1,3-benzodioxin-6-ol

생성물 1

HCID 23332924HCID 23332924, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A mixture of 6-hydroxy-2,4-bis(trichloromethyl)benzo[1,3]dioxin (1.0 g.) and acetic anhydride (10 ml.) was warmed on the steam bath for 15 minutes, and then cooled to ambient temperature. Water (40 ml.) was added, and the mixture stirred for 1 hour. The product was removed by filtration, washed with water, dried and crystallised from ethanol to give 6-acetoxy-2,4-bis(trichloromethyl)benzo[1,3]dioxin, m.p. 142°-144° C.

후처리

  1. temperaturewas warmed on the steam bath for 15 minutes
  2. customThe product was removed by filtration
  3. washwashed with water
  4. customdried
  5. customcrystallised from ethanol

출처 및 근거

ORD 기록
ord-47519d6e0b45497388cd692410609f1e
출처 데이터셋
uspto-grants-1980_11
특허 번호
US04232032

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