Diethylaluminum chloride → 1-Hexene

반응식

[Al](Cl)([CH2:4][CH3:5])CC.[H][H].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]C>>[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH3:14].[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:4]=[CH2:5]

참가 물질

반응물 3

HCID 7277Diethylaluminum chloride

HCID 8900Heptane

HCID 178418361HCID 178418361, 화합물

생성물 2

HCID 115971-Hexene

HCID 194601,7-Octadiene

실험 절차

A solution of 985.94 grams (11.715 mole) 1-hexene and 58.24 grams (0.4831 mole) 1,7-octadiene (molar charge ratio 96:4) in 450 grams of heptane was polymerized with Et2AlCl (13.5 millimoles) and AATiCl3 (6.97 millimoles) at 25° C. for 20 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 62 percent, inherent viscosity was 1.6 dl/gram. The composition of monomers in the copolymer was 97.8:2.2 mole ratio from NMR analysis.