Chlorotrimethylsilane → N,N-bis(trimethylsilyl)perfluorooctaneamide

HRID 227365

반응식

HRID 227365 반응식
[F:1][C:2]([F:25])([C:6]([F:24])([F:23])[C:7]([F:22])([F:21])[C:8]([F:20])([F:19])[C:9]([F:18])([F:17])[C:10]([F:16])([F:15])[C:11]([F:14])([F:13])[F:12])[C:3]([NH2:5])=[O:4].[CH3:26][Si:27]([CH3:30])([CH3:29])Cl.CCCCCCCCCCCCCCCC>CCCCCC>[CH3:26][Si:27]([CH3:30])([CH3:29])[N:5]([Si:27]([CH3:30])([CH3:29])[CH3:26])[C:3](=[O:4])[C:2]([F:25])([F:1])[C:6]([F:23])([F:24])[C:7]([F:21])([F:22])[C:8]([F:19])([F:20])[C:9]([F:17])([F:18])[C:10]([F:15])([F:16])[C:11]([F:14])([F:13])[F:12]

참가 물질

5

반응물 3

HCID 6397ChlorotrimethylsilaneHCID 11006HexadecaneHCID 679192,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctanamide

생성물 1

HCID 86615112N,N-bis(trimethylsilyl)perfluorooctaneamide

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

First, perfluorooctaneamide (CF3(CF2)7CONH2) (46 g) was dissolved in n-hexane (300 ml). Thereafter, trimethylchlorosilane (15 ml) was dropped gradually into the solution obtained above, in a dry nitrogen atmosphere. Then this was allowed to react for two hours while being stirred. After the reaction was completed, hexadecane contained in the reaction solution was removed with the evaporator. Thus, N,N-bis(trimethylsilyl)perfluorooctaneamide was obtained.

후처리

  1. customobtained above, in a dry nitrogen atmosphere
  2. customto react for two hours
  3. customwas removed with the evaporator

출처 및 근거

ORD 기록
ord-297020bd8b424536ad1a50bc562a8510
출처 데이터셋
uspto-grants-2009_07
특허 번호
US07560301B2

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