59177-46-7 → Benzamide

HRID 2282781노트

반응식

HRID 2282781 반응식
[H][H].S[C:4]1[CH:12]=[CH:11][C:7]([C:8]([NH2:10])=[O:9])=[CH:6][CH:5]=1>CO.[Au]>[C:8]([NH2:10])(=[O:9])[C:7]1[CH:11]=[CH:12][CH:4]=[CH:5][CH:6]=1

참가 물질

5

반응물 2

HCID 2235161259177-46-7HCID 178418361HCID 178418361, 화합물

생성물 1

HCID 2331Benzamide

시약·촉매·용매 2

HCID 23985Gold촉매HCID 887Methanol용매

실험 절차

Gold substrates were annealed in a hydrogen flame to get rid of contamination and form well ordered Au surfaces. 4-Mercaptobenzamide prepared according to Example 4 was dissolved (1 mM) in methanol and degassed using argon to avoid oxidation of thiols. The insulated tips treated substrates were immersed in this solution for >2 hours. This resulted in the formation of monolayers of benzamide on the surface. Extended functionalization times degraded insulation on the probes so treatment of probes was limited to 2 h. Functionalization of gold substrates was carried out for up to 20 hours.

후처리

  1. temperatureflame
  2. customto get rid of contamination
  3. customform well ordered Au surfaces
  4. customdegassed
  5. additionThe insulated tips treated substrates
  6. waitwere immersed in this solution for >2 hours

출처 및 근거

ORD 기록
ord-9806d765b84c46838e689ae673bf153b
출처 데이터셋
uspto-grants-2015_09
특허 번호
US09140682B2

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