Trichlorosilane → 13-Tetradecenyl trichlorosilane

HRID 2287055

반응식

HRID 2287055 반응식
[Cl:1][SiH:2]([Cl:4])[Cl:3].[CH2:5]=[CH:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH:17]=[CH2:18]>[Hg]>[CH2:18]([Si:2]([Cl:4])([Cl:3])[Cl:1])[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH:6]=[CH2:5]

참가 물질

4

반응물 2

HCID 24811TrichlorosilaneHCID 30875Tetradeca-1,13-diene

생성물 1

HCID 1013154013-Tetradecenyl trichlorosilane수율 30.3%

시약·촉매·용매 1

HCID 23931Mercury촉매

실험 절차

A stirred mixture of 6.8 g (0.05 mole) trichlorosilane and 19.6 g (0.1 mole) 1,13-tetradecadiene was irradiated in a closed quartz tube at 45° C. for 72 hours with two Hanau 70 watt high pressure mercury immersion lamps, emitting a broad spectrum of ultraviolet light. The resulting crude product was then fractionated to yield 5 g (25%) of 13-tetradecenyl trichlorosilane as the monoadduct.

출처 및 근거

ORD 기록
ord-134c120b8f07434480ae7caff1407bc2
출처 데이터셋
uspto-grants-1981_05
특허 번호
US04268682

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