Diethylene Glycol → Isocyanate

HRID 2287106

반응식

HRID 2287106 반응식
[CH2:1](O)[CH2:2]OCCO.[C:8]1([CH2:18][N:19]=[C:20]=[O:21])C(C[N:15]=[C:16]=[O:17])=CC=CC=1.C([C:26]1(C)[C:31]([OH:32])=C(C(C)(C)C)C=CC1)(C)(C)C>>[CH:1]([N:19]([CH:18]=[CH2:8])[C:20]([O:32][CH2:31][CH3:26])=[O:21])=[CH2:2].[N-:15]=[C:16]=[O:17]

참가 물질

5

반응물 3

HCID 8117Diethylene GlycolHCID 3035160Bis(isocyanatomethyl)benzeneHCID 666371922,6-Di-t-butylcresol

생성물 2

HCID 105034IsocyanateHCID 22923006Divinyl urethane

실험 절차

To 53 g of diethylene glycol (0.5 mole) was added 197 g (1.05 mole) of xylylene diisocyanate, and the mixture was reacted at 80° C. for 2 hours. Then 390 g (1.0 mole) of hydroxyethyl tetraphthalyl acrylate (OH value: 146; average molecular weight: 390) represented by the formula ##STR1## wherein n is the average degree of polymerization and was 1.4 and 0.30 g of 2,6-di-t-butyl cresol as a polymerization inhibitor were added. The resulting mixture was reacted at 80° C. while blowing air through the mixture for 8 hours, and thus a divinyl urethane compound with a remaining isocyanate value of 4.8 was obtained.

후처리

  1. customthe mixture was reacted at 80° C. for 2 hours
  2. customthe average degree of polymerization
  3. additionwere added
  4. customThe resulting mixture was reacted at 80° C.
  5. customfor 8 hours

출처 및 근거

ORD 기록
ord-0e7e60685bdd4c449b3dcb6e55bcc146
출처 데이터셋
uspto-grants-1981_05
특허 번호
US04268611

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