Biphenyl → Bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite

HRID 2288999

반응식

HRID 2288999 반응식
[P:1]([O:32]C1C=CC(C(C)(C)C)=CC=1C(C)(C)C)([O:17][C:18]1[CH:23]=[CH:22][C:21]([C:24]([CH3:27])([CH3:26])[CH3:25])=[CH:20][C:19]=1[C:28]([CH3:31])([CH3:30])[CH3:29])[O:2]C1C=CC(C(C)(C)C)=CC=1C(C)(C)C.CC(C1C=C(C(C)(C)C)C2[O:55][P:56](OCCN(CCOP3OC4C(C(C)(C)C)=CC(C(C)(C)C)=CC=4C4C=C(C(C)(C)C)C=C(C(C)(C)C)C=4O3)CCOP3O[C:84]4[C:86]([C:94]([CH3:97])([CH3:96])[CH3:95])=[CH:87][C:88]([C:90]([CH3:93])([CH3:92])[CH3:91])=[CH:89][C:83]=4C4C=C(C(C)(C)C)C=C(C(C)(C)C)C=4O3)[O:57]C3C(C(C)(C)C)=CC(C(C)(C)C)=CC=3C=2C=1)(C)C.OP(OP(O)O)O.C(C1C=C(C(C2C=CC=CC=2)(C)C)C=CC=1[C:181](C1C=CC(C(C2C=CC=CC=2)(C)C)=CC=1C(C1C=CC=CC=1)(C)C)([C:183]([CH2:188][OH:189])([CH2:186][OH:187])[CH2:184][OH:185])[OH:182])(C1C=CC=CC=1)(C)C.P(Cl)(Cl)Cl.C1(C2C=CC=CC=2)C=CC=CC=1.CCCCC1(CC)COP(OC2C(C(C)(C)C)=CC(C(C)(C)C)=CC=2C(C)(C)C)OC1.OP(OP(O)O)O.C(C(CCCCCCCCCCCCCCCCCC)(C(CO)(CO)CO)O)CCCCCCCCCCCCCCCCC>>[OH:2][P:1]([O:32][P:56]([OH:57])[OH:55])[OH:17].[C:28]([C:19]1[CH:20]=[C:21]([C:24]([CH3:27])([CH3:25])[CH3:26])[CH:22]=[CH:23][C:18]=1[C:181]([C:84]1[CH:83]=[CH:89][C:88]([C:90]([CH3:93])([CH3:92])[CH3:91])=[CH:87][C:86]=1[C:94]([CH3:96])([CH3:95])[CH3:97])([C:183]([CH2:188][OH:189])([CH2:186][OH:187])[CH2:184][OH:185])[OH:182])([CH3:29])([CH3:31])[CH3:30]

참가 물질

8

반응물 7

HCID 7095BiphenylHCID 24387Phosphorus trichlorideHCID 91601Tris(2,4-di-tert-butylphenyl) phosphiteHCID 174215Tris[2-[[2,4,8,10-tetra-tert-butyldibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]ethyl]amineHCID 109613692,4,6-Tri-tert-butylphenyl cyclic butylethylpropanediyl phosphiteHCID 1317124162,2-Bis(hydroxymethyl)-3-octadecylhenicosane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphiteHCID 1317218901,1-Bis[2,4-bis(2-phenylpropan-2-yl)phenyl]-2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite

생성물 1

HCID 131721889Bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite

실험 절차

tris (2,4-di-tert-butylphenyl) phosphite (Irgafos 168, Ciba); 2-[[2,4,8,10-tetrakis(1,1-dimethylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]-N,N-bis[2-[[2,4,8,10-tetrakis(1,1-dimethylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]-ethyl]ethanamine (Irgafos 12, Ciba), 2,4,6 tri-t-butylphenyl 2 butyl 2 ethyl 1,3 propane diphosphite (Ultranox 641, GE Specialty Chemicals); bis(2,4-dicumylphenyl) pentaerythritol diphosphite (Doverphos S-9228, Dover Chemical Corporation); bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol-di-phosphite (PEP-36, Amfine Chemical); reaction product of phosphorous trichloride with 1,1'-biphenyl and 2,4 bis (1,1'-dimethyl) phenol (Sandostab P-EPQ, Clariant), 2,4,6 tri-t-butylphenyl 2 butyl 2 ethyl 1,3 propane diphosphite (Ultranox 641, GE Specialty Chemicals); distearyl pentaerythritol diphosphite (Weston 619, GE Specialty Chemicals).

출처 및 근거

ORD 기록
ord-69ef64db95204ada9ccde19a5d89c357
출처 데이터셋
uspto-grants-2000_07
특허 번호
US06090877

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