Diethyl Ether → HCID 21279517, 화합물
반응식
[CH2:1]([S:8][C:9]1[N:13]=[C:12]([SH:14])[NH:11][N:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl[CH2:16][C:17](=O)[CH3:18].CCOCC.C(=O)(O)[O-].[Na+]>C(O)C>[CH2:1]([S:8][C:9]1[N:13]=[C:12]2[S:14][CH:16]=[C:17]([CH3:18])[N:11]2[N:10]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1참가 물질
6
실험 절차
The product of stage (a) (22.3 g) and chloroacetone (9.6 g) were heated in ethanol (120 ml) under reflux for 22 hours. The solution was then reduced under vacuum, and the residue was stirred with a mixture of ether and aqueous sodium bicarbonate. The ether solution was separated, washed with water, dried over magnesium sulphate, and reduced under vacuum to give 24.1 g of the desired product as an orange oil.
후처리
- temperatureunder reflux for 22 hours
- customThe ether solution was separated
- washwashed with water
- dry with materialdried over magnesium sulphate
출처 및 근거
- ORD 기록
- ord-69c3e20a77984705bb93987ed50712d5
- 출처 데이터셋
- uspto-grants-1989_01
- 특허 번호
- US04795483
반응 노트
불러오는 중…