Phosgene → Tetradecyl chloroformate

HRID 229309

반응식

HRID 229309 반응식
[C:1](Cl)([Cl:3])=[O:2].[CH2:5]([OH:19])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]>C1(C)C=CC=CC=1>[Cl:3][C:1]([O:19][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:2]

참가 물질

4

반응물 2

HCID 6371PhosgeneHCID 82091-Tetradecanol

생성물 1

HCID 92493Tetradecyl chloroformate수율 98.7%

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

29 ml of a 20% toluene solution of phosgene (55.98 mmoles) was added to tetradecyl alcohol (4 g, 18.66 mmoles) and the reaction mixture was left to stand for 20 hours under stirring at room temperature. After solvent evaporation, the residue was taken up with hexane and evaporated to dryness (several times) to give 5.1 g product as colourless liquid.

후처리

  1. waitthe reaction mixture was left
  2. customAfter solvent evaporation
  3. customevaporated to dryness (several times)

출처 및 근거

ORD 기록
ord-2d13dd51f1cf434baf640ddf914ee0aa
출처 데이터셋
uspto-grants-2009_07
특허 번호
USRE040861E1

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