Hydrazine hydrate (1:1) → HCID 54417124, 화합물
반응식
[CH2:1]([C:3](=[CH:18][CH:19]([CH3:21])[CH3:20])[CH:4]=[CH:5][CH2:6][N:7]1C(=O)C2=CC=CC=C2C1=O)[CH3:2].O.NN>C(O)C>[CH2:1]([C:3](=[CH:18][CH:19]([CH3:20])[CH3:21])[CH:4]=[CH:5][CH2:6][NH2:7])[CH3:2]참가 물질
4
실험 절차
A mixture of N-(4-ethyl-6-methyl-2,4-heptadiene-1-yl)phthalimide (17.62 g), hydrazine monohydrate (9.9 g), and ethanol (700 ml) was refluxed for 90 minutes under nitrogen atmosphere. The reaction mixture was evaporated in vacuo. The residue was dissolved in 10% aqueous potassium carbonate solution and extracted with ethyl acetate. The organic extract was washed with brine, dried over anhydrous magnesium sulfate, and evaporated to give 4-ethyl-6-methyl-2,4-heptadiene-1-ylamine as an oil.
후처리
- temperaturewas refluxed for 90 minutes under nitrogen atmosphere
- customThe reaction mixture was evaporated in vacuo
- dissolutionThe residue was dissolved in 10% aqueous potassium carbonate solution
- extractionextracted with ethyl acetate
- extractionThe organic extract
- washwas washed with brine
- dry with materialdried over anhydrous magnesium sulfate
- customevaporated
출처 및 근거
- ORD 기록
- ord-e7713d92fafa4cbab37fa0af2be800af
- 출처 데이터셋
- uspto-grants-1997_11
- 특허 번호
- US05691366
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