N-(4-ethyl-2-hydroxyimino-5-nitro-3-hexen-1-yl)-3-pyridinecarboxamide → HCID 53837090, 화합물

HRID 2295028노트

반응식

HRID 2295028 반응식
[CH2:1]([C:3]([CH:18]([N+:20]([O-:22])=[O:21])[CH3:19])=[CH:4][C:5](=[N:16][OH:17])[CH2:6][NH:7][C:8]([C:10]1[CH:11]=[N:12][CH:13]=[CH:14][CH:15]=1)=[O:9])[CH3:2].ClC1C=CC=C(C(OO)=[O:31])C=1.C(Cl)(Cl)Cl>CC(C)=O>[CH2:1]([C:3]([CH:18]([N+:20]([O-:22])=[O:21])[CH3:19])=[CH:4][C:5](=[N:16][OH:17])[CH2:6][NH:7][C:8]([C:10]1[CH:11]=[N+:12]([O-:31])[CH:13]=[CH:14][CH:15]=1)=[O:9])[CH3:2]

참가 물질

5

반응물 3

HCID 4532N-(4-ethyl-2-hydroxyimino-5-nitro-3-hexen-1-yl)-3-pyridinecarboxamideHCID 6212ChloroformHCID 70297m-Chloroperbenzoic acid

생성물 1

HCID 53837090HCID 53837090, 화합물

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

A mixture of N-(4-ethyl-2-hydroxyimino-5-nitro-3-hexen-1-yl)-3-pyridinecarboxamide (306 mg), 3-chloroperbenzoic acid (323 mg), chloroform (15 ml) and acetone (40 ml) was stirred at room temperature for 10 hours. The resulting precipitates were collected and washed with acetone to give N-(4-ethyl-2-hydroxyimino-5-nitro-3-hexen-1-yl)-3-pyridinecarboxamide 1-oxide.

후처리

  1. customThe resulting precipitates
  2. customwere collected
  3. washwashed with acetone

출처 및 근거

ORD 기록
ord-870e8cdd85b044ba8d57e8b102ae58dd
출처 데이터셋
uspto-grants-1997_11
특허 번호
US05691366

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