Methyl Isocyanate → HCID 53719918, 화합물
반응식
[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[C:3](=[N:8][OH:9])[S:2]2.[CH3:10][N:11]=[C:12]=[O:13]>C(Cl)Cl>[CH3:10][NH:11][C:12]([O:9][N:8]=[C:3]1[CH:4]2[CH2:7][CH:1]([CH2:6][CH2:5]2)[S:2]1)=[O:13]참가 물질
4
실험 절차
A solution of 6.6 g (0.046 m) of 2-thiabicyclo[2.2.1]heptan-3-one oxime, 2.9 g (0.05 m) of methyl isocyanate, and 60 ml of methylene chloride was stirred at room temperature for 17 hours. Removal of solvent gave 9.1 g of yellow-tan solid which was purified by dry column chromatography on silica gel using ether-acetone as eluent. There was obtained 5.2 g of the title product as a cream colored solid, m. 121°-2° C.
후처리
- customRemoval of solvent
출처 및 근거
- ORD 기록
- ord-5886146fd26544408d3bec35c276da2f
- 출처 데이터셋
- uspto-grants-1984_01
- 특허 번호
- US04424213
반응 노트
불러오는 중…