1-Butanol → HCID 13255805, 화합물

HRID 2295912노트

반응식

HRID 2295912 반응식
[OH-:1].[K+].Cl[C:4](Cl)(Cl)[CH2:5][C:6]1[C:11]([Cl:12])=[CH:10][C:9]([Cl:13])=[CH:8][C:7]=1[Cl:14].[CH2:17]([OH:21])[CH2:18][CH2:19][CH3:20]>>[Cl:14][C:7]1[CH:8]=[C:9]([Cl:13])[CH:10]=[C:11]([Cl:12])[C:6]=1[CH2:5][C:4]([O:21][CH2:17][CH2:18][CH2:19][CH3:20])=[O:1]

참가 물질

4

반응물 3

HCID 2631-ButanolHCID 14797Potassium HydroxideHCID 204743061,3,5-Trichloro-2-(2,2,2-trichloroethyl)benzene

생성물 1

HCID 13255805HCID 13255805, 화합물

실험 절차

A 9.0 g. portion of potassium hydroxide of the grade described in the examples above was combined with 50 ml. of butanol, and the mixture was stirred for 15 minutes. To it was added 5 g. of 1,1,1-trichloro-2-(2,4,6-trichlorophenyl)ethane, and the mixture was stirred under reflux at 115° for 7 hours. It was then cooled to ambient temperature overnight, and worked up substantially as described in Example 4 above to obtain 3.9 g. of product, 96% pure by vapor phase chromatography. The product was distilled at 155°-162° under 0.35 torr to obtain 3.4 g. of purified product.

후처리

  1. additionTo it was added 5 g
  2. temperatureunder reflux at 115° for 7 hours
  3. customto obtain 3.9 g
  4. distillationThe product was distilled at 155°-162° under 0.35 torr
  5. customto obtain 3.4 g

출처 및 근거

ORD 기록
ord-0775402b18354844b3e3e4c86865cdef
출처 데이터셋
uspto-grants-1984_01
특허 번호
US04426536

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