Butyl phenyl ether → HCID 20472103, 화합물

HRID 2296263

반응식

HRID 2296263 반응식
[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[P:12]12(SP3(SP(SP(S3)(S1)=S)(=S)[S:14]2)=S)=[S:13]>CCCCCC>[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9]([P:12](=[S:14])=[S:13])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4]

참가 물질

4

반응물 2

HCID 14311Butyl phenyl etherHCID 14817Phosphorus sulfide (P2S5)

생성물 1

HCID 20472103HCID 20472103, 화합물

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

n-Butyloxybenzene (Ic) and P4S10 (in a molar ratio of 10:1) were stirred for six hours at 150° C. under anhydrous conditions. The mixture was cooled, hexane was added, and the reaction flask was left for two days at 5° C. The resulting precipitate was recovered by filtration, washed with anhydrous hexane and dried. The yield of product was 37% of theory; after recrystallization from chloroform/petroleum ether it melted at 142°-4° C. Its solubility in tetrahydrofuran was found to be 5 gms/100 ml at room temperature.

후처리

  1. temperatureThe mixture was cooled
  2. filtrationThe resulting precipitate was recovered by filtration
  3. washwashed with anhydrous hexane
  4. customdried
  5. customafter recrystallization from chloroform/petroleum ether it melted at 142°-4° C
  6. customat room temperature

출처 및 근거

ORD 기록
ord-528df5a62ab441a5872b6794550b2c2b
출처 데이터셋
uspto-grants-1984_01
특허 번호
US04428889

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