p-Fluorotoluene-alpha-thiol → HCID 86593386, 화합물

HRID 2308047노트

반응식

HRID 2308047 반응식
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[C:9]#[CH:10].[F:11][C:12]1[CH:19]=[CH:18][C:15]([CH2:16][SH:17])=[CH:14][CH:13]=1.[Na]>>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1/[CH:9]=[CH:10]\[CH:16]([S:17][CH:16](/[CH:10]=[CH:9]\[C:3]1[CH:4]=[CH:5][C:6]([Cl:8])=[CH:7][C:2]=1[Cl:1])[C:15]1[CH:18]=[CH:19][C:12]([F:11])=[CH:13][CH:14]=1)[C:15]1[CH:18]=[CH:19][C:12]([F:11])=[CH:13][CH:14]=1

참가 물질

4

반응물 3

HCID 85171p-Fluorotoluene-alpha-thiolHCID 5360545SodiumHCID 126397532,4-Dichloro-1-ethynylbenzene

생성물 1

HCID 86593386HCID 86593386, 화합물

실험 절차

A solution of 2,4-dichlorophenylacetylene (0.02 mol), 4-fluorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) is subjected to the General Procedure to form (Z)-2,4-dichlorostyryl-4-fluorobenzylsulfide. The title compound is obtained following oxidation of the sulfide, according to the General Procedure.

출처 및 근거

ORD 기록
ord-3c8ddb32184145a2b9cd858cf5cc8faf
출처 데이터셋
uspto-grants-2004_12
특허 번호
US06833480B2

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