Caprolactam → Laurocapram

HRID 2309070

반응식

HRID 2309070 반응식
[O-2].[Na+].[Na+].C[Si](C)(C)[N:6]1[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][C:7]1=[O:13].[Na].C1(=O)NCCCCC1.[CH2:25](Br)[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36]>COCCOC>[CH2:36]([N:6]1[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][C:7]1=[O:13])[CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH3:25]

참가 물질

7

반응물 5

HCID 7768CaprolactamHCID 89191-BromododecaneHCID 73971Sodium oxideHCID 5360545SodiumHCID 114239991-Trimethylsilanyl-azepan-2-one

생성물 1

HCID 42981Laurocapram

시약·촉매·용매 1

HCID 80711,2-Dimethoxyethane용매

실험 절차

3.1 g (0.05 mol) of sodium oxide (Na2O) are suspended in 150 ml of 1,2-dimethoxyethane, and then 18.5 g (0.1 mol) of N-trimethylsilylcaprolactam are added. The reaction mixture is stirred at 50° C. for two hours, during which the voluminous precipitate of the sodium salt of the caprolactam forms. Then 24.9 g (0.1 mol) of n-dodecyl bromide are added, and the mixture is stirred and heated under reflux for 20 hours. The working-up is carried out as indicated in Example 1.

후처리

  1. temperatureheated
  2. temperatureunder reflux for 20 hours

출처 및 근거

ORD 기록
ord-f493cb7f940142b18569cc6c29bf1021
출처 데이터셋
uspto-grants-1987_09
특허 번호
US04692523

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