참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Epichlorohydrin | HCID 7835 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 12-Cyclohexyldodecanol | HCID 14877785 | — |
| 촉매 | Hexadecyltrimethylammonium chloride | HCID 8154 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 1,2-Epoxy-3-(12-cyclohexyldodecyloxy)propane | HCID 14877786 | 71.2% |
반응 단계
A mixture containing 26.5 g of 12-cyclohexyldodecanol, 27.4 g of epichlorohydrin, 52.6 g of a 50% aqueous sodium hydroxide solution, 2.0 g of cetyltrimethylammonium chloride and 300 ml of toluene is stirred at 60° C. for 24 hours. The resulting reaction mixture is then washed with water, dried and concentrated to leave a residue which in turn is purified by silica gel chromatography to obtain 22.8 g of the captioned compound as a colorless oily substance.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04845219 |
|---|
| 출처 데이터셋 | uspto-grants-1989_07 |
|---|
| ORD ID | ord-8d23ce74afe44c119a199939851f91c9 |
|---|
| 출처 메모 | uspto-grants-1989_07 |
|---|
