Bisphenol A → 2,2-Bis[4-(3-nitrophenoxy)phenyl]propane

HRID 231618

반응식

HRID 231618 반응식
O[C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:11]2[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][CH:12]=2)([CH3:10])[CH3:9])=[CH:4][CH:3]=1.[N+]([C:21]1[CH:26]=[CH:25][CH:24]=[C:23]([N+:27]([O-:29])=[O:28])[CH:22]=1)([O-])=O.[C:30](=[O:33])([O-])[O-].[K+].[K+]>CN(C)C=O>[N+:27]([C:23]1[CH:22]=[C:21]([CH:26]=[CH:25][CH:24]=1)[O:17][C:14]1[CH:15]=[CH:16][C:11]([C:8]([C:5]2[CH:6]=[CH:7][C:2]([O:33][C:30]3[CH:26]=[CH:21][CH:22]=[C:23]([N+:27]([O-:29])=[O:28])[CH:24]=3)=[CH:3][CH:4]=2)([CH3:10])[CH3:9])=[CH:12][CH:13]=1)([O-:29])=[O:28]

참가 물질

5

반응물 3

HCID 6623Bisphenol AHCID 74521,3-DinitrobenzeneHCID 11430Potassium Carbonate

생성물 1

HCID 22460842,2-Bis[4-(3-nitrophenoxy)phenyl]propane수율 93.5%

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

반응 조건

온도
65 °C

실험 절차

A 1 liter glass reaction vessel was charged with 85.6 grams (0.375 mol) of 2,2-bis(4-hydroxyphenyl)propane, 151.2 grams (0.9 mol) of m-dinitrobenzene, 124.6 grams of potassium carbonate and 660 ml of N,N-dimethylformamide. The mixture was reacted for 10 hours at a temperature of 145°-150° C. After completing the reaction, the resultant mixture was cooled and filtered to remove potassium nitrite. The solvent was distilled off from the filtrate under reduced pressure. The residue was cooled to 65° C., added with 450 ml of methanol and stirred for an hour. The resulted crystals were filtered, washed with water, washed with methanol, and dried to obtain 164.8 grams (93.5% yield) of 2,2-bis[4-(3-nitrophenoxy)phenyl]propane as yellow brown crystals.

후처리

  1. customThe mixture was reacted for 10 hours at a temperature of 145°-150° C
  2. customthe reaction
  3. filtrationfiltered
  4. customto remove potassium nitrite
  5. distillationThe solvent was distilled off from the filtrate under reduced pressure
  6. additionadded with 450 ml of methanol
  7. filtrationThe resulted crystals were filtered
  8. washwashed with water
  9. washwashed with methanol
  10. customdried

출처 및 근거

ORD 기록
ord-6ec9bfb87cb4492aaf86407e8c3c5744
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04847311

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