L-Ascorbic Acid → L-(-)-Ornithine

HRID 232510

반응식

HRID 232510 반응식
[NH2:1][CH:2]([C:10]([OH:12])=[O:11])[CH2:3][CH2:4][CH2:5][NH:6]C(=N)N.O=C1O[C@H]([C@H](CO)O)C(O)=C1O.N[C@H](C(O)=O)CCCNC(=N)N>[O-]S([O-])(=O)=O.[Mn+2].O>[NH2:1][C@H:2]([C:10]([OH:12])=[O:11])[CH2:3][CH2:4][CH2:5][NH2:6]

참가 물질

5

반응물 3

HCID 54670067L-Ascorbic AcidHCID 178418600HCID 178418600, 화합물2회HCID 178512957HCID 178512957, 화합물

생성물 1

HCID 6262L-(-)-Ornithine

시약·촉매·용매 1

HCID 177577Manganese sulfate monohydrate촉매

실험 절차

100 ml of a 1.25 molar, racemic solution of DL-arginine are mixed with 5·10-4 mol/l MnSO4.H2O, 2.5·10-4 mol/1 ascorbic acid and 14.0 mg L-arginase (=10000 U/(l·mol L-Arg)). After 22 hours, the conversion was 50% of the original amount of arginine and a corresponding amount of ornithine had been produced.

출처 및 근거

ORD 기록
ord-ecd33c8f4e6f4c3a97da7f438e9ae949
출처 데이터셋
uspto-grants-1997_01
특허 번호
US05591613

연결된 노트

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