Stannous Chloride → 5-Bromo-2-(phenylthio)benzenamine

반응식

[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[C:4]([N+:15]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[C:4]([NH2:15])[CH:3]=1

참가 물질

반응물 2

HCID 24479Stannous Chloride

HCID 14531509(4-Bromo-2-nitrophenyl)(phenyl)sulfane

생성물 1

HCID 284015215-Bromo-2-(phenylthio)benzenamine수율 100%

실험 절차

The product from Example 121b (2.0 g, 6.45 mmol) was reduced with SnCl2 following the procedure from Example 1f giving the title compound as a clear oil (1.8 g, 100%).

출처 및 근거

ORD 기록: ord-8c9f9dbaeef44a7496932f9082654c2e
출처 데이터셋: uspto-grants-2010_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07763731B2

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