Triethylamine → alpha-D-Mannopyranose

HRID 2369765

반응식

HRID 2369765 반응식
C1(NC2C(=O)C(=O)C=2)C=CC=CC=1.[OH:14][C@H:15]1[O:23][C@H:22]([CH2:24][OH:25])[C@@H:20]([OH:21])[C@H:18]([OH:19])[C@@H:16]1[OH:17].C(N(CC)CC)C>C(O)C.C(O)C.O.O>[OH:14][C@H:15]1[O:23][C@H:22]([CH2:24][OH:25])[C@@H:20]([OH:21])[C@H:18]([OH:19])[C@@H:16]1[OH:17]

참가 물질

6

반응물 2

HCID 8471TriethylamineHCID 86678081alpha-Mannose phenylaminocyclobutenedione2회

생성물 1

HCID 185698alpha-D-Mannopyranose

시약·촉매·용매 3

HCID 702Ethanol용매2회HCID 962Water용매HCID 19096565Water ethanol용매

실험 절차

Nanoparticles DB052 (200 mg) were stirred up by ultrasounds for 30 minutes in ethanol (5 mL). α-mannose phenylaminocyclobutenedione derivatives (71 mg, 1.8 10−4 mol, structure here above) was dissolved in an ethanol/water mixture (10 ml, 3/2). The α-mannose phenylaminocyclobutenedione derivative solution was added dropwisely to the nanoparticle suspension. Triethylamine (500 μL) was added, and the suspension was stirred for 18 hours. After centrifugation, the nanoparticles were dispersed in water and centrifuged (3 cycles), then dispersed in ethanol and centrifugated (two cycles). Functionalized nanoparticles (DB069) were obtained (200 mg).

출처 및 근거

ORD 기록
ord-d956c0b2d6f44e7aad3939dd97a400b7
출처 데이터셋
uspto-grants-2014_04
특허 번호
US08709747B2

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