3-Methyl-2-cyclohexen-1-one → 3-Methyl-2-cyclohexen-1-one

HRID 237757

반응식

HRID 237757 반응식
[CH3:1][C:2]1[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH:3]=1.[CH3:9][Mg]I>C(OCC)C>[CH3:1][C:2]1[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH:3]=1.[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][CH2:5][C:4](=[O:8])[CH2:3]1

참가 물질

5

반응물 2

HCID 145113-Methyl-2-cyclohexen-1-oneHCID 178418373HCID 178418373, 화합물

생성물 2

HCID 145113-Methyl-2-cyclohexen-1-oneHCID 76322Cyclohexanone, 3,3-dimethyl-

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

First, 3-methyl-cyclohexenone was prepared in accordance with the procedures of Jirgensons et. al., Euro. J. Med. Chem. 35 (2000) 555-565. Then, 3-methyl-cyclohexenone was reacted with methyl magnesium iodide in the presence of cuprous chloride in diethyl ether to obtain the title compound.

출처 및 근거

ORD 기록
ord-f2ed5d56b2764e25bcbeb6e69c3a3e53
출처 데이터셋
uspto-grants-2014_02
특허 번호
US08642603B2

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