Sodium Hydroxide → Sodium diallyloxyacetate

HRID 2379242노트

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HRID 2379242 반응식
[CH2:1]([O:4][CH:5]([O:12][CH2:13][CH:14]=[CH2:15])[C:6]([O:8]CC=C)=[O:7])[CH:2]=[CH2:3].[OH-].[Na+:17]>C1(C)C=CC=CC=1.O>[CH2:13]([O:12][CH:5]([O:4][CH2:1][CH:2]=[CH2:3])[C:6]([O-:8])=[O:7])[CH:14]=[CH2:15].[Na+:17]

참가 물질

5

반응물 2

HCID 14798Sodium HydroxideHCID 18958141Prop-2-en-1-yl bis[(prop-2-en-1-yl)oxy]acetate

생성물 1

HCID 5173263Sodium diallyloxyacetate

시약·촉매·용매 2

HCID 962Water용매HCID 1140Toluene용매

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온도
30 °C

실험 절차

21.2 g (0.1 mole) of allyl diallyloxyacetate is dissolved in 42 g of toluene then 3.92 g (98 mmoles) of sodium hydroxide dissolved in 50 g of water is introduced into this solution. This bipbase reaction medium is agitated vigorously for 30 minutes at 30° C., then decanted and the aqueous phase is collected and subjected to a vacuum distillation to eliminate the freed allyl alcohol by azeotropic distillation. The aqueous phase is then poured into acetone to precipitate the expected sodium diallyloxyacetate.

후처리

  1. additionis introduced into this solution
  2. customThis bipbase reaction medium
  3. customdecanted
  4. customthe aqueous phase is collected
  5. distillationsubjected to a vacuum distillation
  6. distillationby azeotropic distillation
  7. additionThe aqueous phase is then poured into acetone
  8. customto precipitate the expected sodium diallyloxyacetate

출처 및 근거

ORD 기록
ord-6f9ae786a9ec4e03b2b3cebb29066029
출처 데이터셋
uspto-grants-1994_11
특허 번호
US05360881

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