Potassium Carbonate → p-Methoxybenzamidoxime
반응식
[CH3:1][O:2][C:3]1[CH:10]=[CH:9][C:6]([C:7]#[N:8])=[CH:5][CH:4]=1.Cl.[NH2:12][OH:13].C(=O)([O-])[O-].[K+].[K+]>C(O)C>[CH3:1][O:2][C:3]1[CH:10]=[CH:9][C:6]([C:7](=[N:12][OH:13])[NH2:8])=[CH:5][CH:4]=1참가 물질
5
실험 절차
13.32 g (0.1 mol) 4-methoxybenzonitrile, 20.85 g (0.3 mol) of hydroxylamine hydrochloride and 41.40 g (0.3 mol) potassium carbonate was added to 400 mL absolute ethanol and refluxed 21 hours. The product was filtered and recrystallized from methanol to give 3.12 g (0.02 mol) of 4-methoxybenzamide oxime.
후처리
- temperaturerefluxed 21 hours
- filtrationThe product was filtered
- customrecrystallized from methanol
출처 및 근거
- ORD 기록
- ord-147606ac386542db85baec4e3378b6cd
- 출처 데이터셋
- uspto-grants-1994_11
- 특허 번호
- US05364865
반응 노트
불러오는 중…