Azobisisobutyronitrile → Isooctyl Acrylate Acrylamide Vinyl Acetate

HRID 238252

반응식

HRID 238252 반응식
[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[C:14]([NH2:18])(=[O:17])[CH:15]=[CH2:16].[C:19]([O:22][CH:23]=[CH2:24])(=[O:21])[CH3:20].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N.CC(N=NC(C#N)(C)C)(C#N)C>C(OCC)(=O)C.CO.C(OCC)(=O)C.CO>[C:14]([NH2:18])(=[O:17])[CH:15]=[CH2:16].[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[C:19]([O:22][CH:23]=[CH2:24])(=[O:21])[CH3:20]

참가 물질

9

반응물 5

HCID 6547AzobisisobutyronitrileHCID 6579AcrylamideHCID 7904Vinyl AcetateHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)HCID 165746Isooctyl acrylate

생성물 1

HCID 86608178Isooctyl Acrylate Acrylamide Vinyl Acetate

시약·촉매·용매 3

HCID 887Methanol용매HCID 8857Ethyl Acetate용매2회HCID 21584119Ethylacetate methanol용매

실험 절차

A master batch was prepared by combining 621.0 g of isooctyl acrylate, 41.4 g of acrylamide, 165.6 g of vinyl acetate, 1.656 g of 2,2′-azobis(2,4-dimethylpentanenitrile) (available from the DuPont Company as Vazo™ 52), 884.52 g of ethyl acetate and 87.48 g of methanol. A 400 g portion of the resulting solution was placed in an amber quart bottle. The bottle was purged for two minutes with nitrogen at a flow rate of one liter per minute. The bottle was sealed and placed in a rotating water bath at 45° C. for twenty-four hours to effect essentially complete polymerization. The copolymer was diluted with 250 g of ethyl acetate/methanol (90/10) to 26.05% solids and had a measured inherent viscosity of 1.27 dl/g in ethyl acetate at a concentration of 0.15 g/dl. Its Brookfield viscosity was 5580 centipoise.

후처리

  1. customA master batch was prepared
  2. customThe bottle was purged for two minutes with nitrogen at a flow rate of one liter per minute
  3. customThe bottle was sealed
  4. waitplaced in a rotating water bath at 45° C. for twenty-four hours
  5. custompolymerization

출처 및 근거

ORD 기록
ord-ee551ed3ea06471aa14613e93de0ae1c
출처 데이터셋
uspto-grants-2014_02
특허 번호
US08642616B2

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