N-Hydroxyphthalimide → Cyclohexylbenzene

HRID 23827

반응식

HRID 23827 반응식
ON1C(=O)C2=CC=CC=C2C1=O.[CH:13]1([C:19]2([CH:27]=[CH:26][CH:25]=[CH:24][CH2:23]2)C[O:21][OH:22])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1.[CH:28]1([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[CH2:33][CH2:32][CH2:31][CH2:30][CH2:29]1>>[O-:21][OH:22].[CH:19]1([C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27]1.[CH:34]1([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)[CH2:35][CH2:36][CH2:37][CH2:38][CH2:39]1

참가 물질

5

반응물 3

HCID 10665N-HydroxyphthalimideHCID 13229CyclohexylbenzeneHCID 225906441-Cyclohexylbenzyl hydroperoxide

생성물 2

HCID 13229CyclohexylbenzeneHCID 86589629Cyclohexylbenzene hydroperoxide

실험 절차

0.3 mmol of N-hydroxyphthalimide and 0.6 mmol of 1-cyclohexylbenzyl hydroperoxide are added at a temperature of 110° C. to 30 mmol of cyclohexylbenzene in a round-bottomed flask having an attached reflux condenser. The reaction mixture is stirred for 8 hours at said temperature under an oxygen atmosphere of 1 bar. 1-cyclohexylbenzene hydroperoxide is obtained at a selectivity of 96.2% at a cyclohexylbenzene conversion rate of 28.6%.

후처리

  1. temperaturean attached reflux condenser

출처 및 근거

ORD 기록
ord-9972f8ebd5db4a888fcaceca1be0fafb
출처 데이터셋
uspto-grants-2005_02
특허 번호
US06852893B2

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