Diphenylphosphoryl azide → (R)-alpha-Propylpiperonylazide

HRID 2393732노트

반응식

HRID 2393732 반응식
C(C(O)C1C=CC2OCOC=2C=1)CC.P(N=[N+]=[N-])(OC1C=CC=CC=1)(OC1C=CC=CC=1)=O.[CH2:34]([CH:37]([N:47]=[N+:48]=[N-:49])[C:38]1[CH:46]=[CH:45][C:44]2[O:43][CH2:42][O:41][C:40]=2[CH:39]=1)[CH2:35][CH3:36]>C1(C)C=CC=CC=1>[CH2:34]([C@@H:37]([N:47]=[N+:48]=[N-:49])[C:38]1[CH:46]=[CH:45][C:44]2[O:43][CH2:42][O:41][C:40]=2[CH:39]=1)[CH2:35][CH3:36]

참가 물질

5

반응물 3

HCID 123414Diphenylphosphoryl azideHCID 10375365HCID 10375365, 화합물HCID 18977048HCID 18977048, 화합물

생성물 1

HCID 10680381(R)-alpha-Propylpiperonylazide

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

tR : α-propyl-piperonyl alcohol, 5.9 min.; toluene, 7.8 min.; (PhO)2P(O)N3, 9.3 min.; olefin side-product, 10.6 min.; α-propyl-piperonylazide, 11.4 min.

출처 및 근거

ORD 기록
ord-c60bb8129bd1420183f8f2ba612550c8
출처 데이터셋
uspto-grants-1998_09
특허 번호
US05808056

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