Diazomethane → HCID 19430584, 화합물

HRID 2399282노트

반응식

HRID 2399282 반응식
[OH:1][C:2]1[CH:10]=[CH:9][C:8]([C:11]([CH3:15])([CH3:14])[CH2:12][CH3:13])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[N+](=[CH2:18])=[N-]>>[CH3:18][O:5][C:4](=[O:6])[C:3]1[CH:7]=[C:8]([C:11]([CH3:14])([CH3:15])[CH2:12][CH3:13])[CH:9]=[CH:10][C:2]=1[OH:1]

참가 물질

3

반응물 2

HCID 9550DiazomethaneHCID 2687425-tert-amylsalicylic acid

생성물 1

HCID 19430584HCID 19430584, 화합물

실험 절차

Following the procedure of Schmitt et al., Synthesis, 1984, 758-760; and treating the resulting 2-hydroxy-5-(1,1-dimethylpropyl)benzoic acid with diazomethane gave the title compound. 1H NMR (250 MHz, CDCl3) δ10.61 (s, 1H), 7.75 (d, 1H), 7.44 (dd, 1H), 6.92 (d, 1H), 3.95 (s, 3H), 1.61 (q, 2H), 1.26 (s, 6H), 0.67 (t, 3H).

후처리

  1. customthe procedure of Schmitt et al., Synthesis, 1984, 758-760

출처 및 근거

ORD 기록
ord-f44abc08b31b45d3b04d675e1f275aaa
출처 데이터셋
uspto-grants-1995_09
특허 번호
US05447957

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