2-Methoxyaniline → N-(2-methoxyphenyl)-3-nitrobenzenesulfonamide

반응식

[CH3:1][O:2][C:3]1[C:4]([NH2:9])=[CH:5][CH:6]=[CH:7][CH:8]=1.[N+:10]([C:13]1[CH:14]=[C:15]([S:19](Cl)(=[O:21])=[O:20])[CH:16]=[CH:17][CH:18]=1)([O-:12])=[O:11]>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[NH:9][S:19]([C:15]1[CH:16]=[CH:17][CH:18]=[C:13]([N+:10]([O-:12])=[O:11])[CH:14]=1)(=[O:20])=[O:21]

참가 물질

반응물 2

HCID 70002-Methoxyaniline

HCID 84763-Nitrobenzenesulfonyl chloride

생성물 1

HCID 2834884N-(2-methoxyphenyl)-3-nitrobenzenesulfonamide수율 89.5%

실험 절차

Using o-anisidine (1.0 ml, 8.55 mmol) and 3-nitrobenzenesulfonyl chloride (1.95 g, 8.55 mmol), the procedure of Reference Example 2 was repeated to obtain 2.36 g (89.5%) of the title compound in the form of light yellow needle crystals.

출처 및 근거

ORD 기록: ord-df69311069264a20a142aa147b4fbb47
출처 데이터셋: uspto-grants-1998_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05728835

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