Potassium Carbonate → 9-Decenyl bis(pentafluoroethyl)phosphinite

HRID 241314

반응식

HRID 241314 반응식
[CH2:1]([OH:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH2:10].C([O-])([O-])=O.[K+].[K+].[F:18][C:19]([P:25](Cl)[C:26]([F:32])([F:31])[C:27]([F:30])([F:29])[F:28])([F:24])[C:20]([F:23])([F:22])[F:21]>C(Cl)Cl>[F:24][C:19]([P:25]([C:26]([F:31])([F:32])[C:27]([F:28])([F:29])[F:30])[O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH2:10])([F:18])[C:20]([F:23])([F:22])[F:21]

참가 물질

5

반응물 3

HCID 11430Potassium CarbonateHCID 256129-Decen-1-olHCID 2757428Bis(pentafluoroethyl)phosphinous chloride2회

생성물 1

HCID 866538149-Decenyl bis(pentafluoroethyl)phosphinite

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

0.31 g (1.9 mmol) of 9-decen-1-ol is initially introduced in CH2Cl2 with excess K2CO3, and 0.64 g (2.1 mmol) of bis(pentafluoroethyl)phosphinous acid chloride, (C2F5)2PCl, is condensed in. After the mixture has been stirred at room temperature for 30 minutes, the precipitate is filtered off, and volatile substances are removed in vacuo. The product, 9-decenyl bis(pentafluoroethyl)phosphinite, remains as a colourless, oily liquid, which is characterised by spectroscopy.

후처리

  1. customcondensed in
  2. filtrationthe precipitate is filtered off
  3. customvolatile substances are removed in vacuo

출처 및 근거

ORD 기록
ord-c98278044eb643478b8fe43038cd321c
출처 데이터셋
uspto-grants-2014_02
특허 번호
US08648202B2

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